Hot Review: Synthesising alkoxyamine onto activated olefins

Intermolecular radical 1,2-addition of the BlocBuilder MA alkoxyamine onto activated olefins: a versatile tool for the synthesis of complex macromolecular architecture: In this Hot Review Didier Gigmes et Al., discuss the potential of the intermolecular radical 1,2-addition from the commercially available BlocBuilder MA alkoxyamine onto activated olefins to synthesize either new functionalized alkoxyamines or various macromolecular architectures.

Graphical abstract: Intermolecular radical 1,2-addition of the BlocBuilder MA alkoxyamine onto activated olefins: a versatile tool for the synthesis of complex macromolecular architecture

Didier Gigmes, Pierre-Emmanuel Dufils, David Glé, Denis Bertin, Catherine Lefay and Yohann Guillaneuf, Polym. Chem., 2011, DOI:10.1039/C1PY00057H, Advance Article

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