Archive for February, 2011

Hot Articles on spongy solar cells, nanoflakes supercapacitors and a nonlinear optical material

Spongy structure of CdS nanocrystals decorated with dye molecules for semiconductor sensitized solar cells. Tao Ling, Ming-Ke Wu, Kai-Yang Niu, Jing Yang, Zhi-Ming Gao, Jing Sun and Xi-Wen Du, J. Mater. Chem., 2011, DOI: 10.1039/C0JM03530K (Advance Article)

This paper reports the work of Xi-Wen Du at Tianjin University and co-workers as they exploit a new structure of semiconductor sensitized solar cells, where CdS nanocrystals are assembled into a spongy structure and decorated with organic molecules to serve as photoanode. The spongy solar cells show higher absorption and conversion efficiency than traditional semiconductor sensitized solar cells the team claim. 

Graphical abstract: Spongy structure of CdS nanocrystals decorated with dye molecules for semiconductor sensitized solar cells

 

Graphical abstract: A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10. Single crystals of Li3Cs2B5O10 have been synthesized and its structure determined by single-crystal X-ray diffraction.

Yun Yang, Shilie Pan, Xueling Hou, Chuanyi Wang, Kenneth R. Poeppelmeier, Zhaohui Chen, Hongping Wu and Zhongxiang Zhou, J. Mater. Chem., 2011, DOI: 10.1039/C0JM03187A (Advance Article)

Graphical abstract: Hierarchical self-assembly of ultrathin nickel hydroxide nanoflakes for high-performance supercapacitorsHierarchical self-assembly of ultrathin nickel hydroxide nanoflakes for high-performance supercapacitors. Hao Jiang, Ting Zhao, Chunzhong Li and Jan Ma, J. Mater. Chem., 2011, DOI:10.1039/C0JM03830J (Advance Article)

Ultrathin Ni(OH)2 hierarchical nanostructures have been successfully designed. The team behind the research led by Chunzhong Li and Jan Ma claim they show excellent electrochemical capacitive behavior.

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Hybrid Materials themed issues from RSC Publishing

 Did you read the recent themed issue in Journal of Materials Chemistry on the topic of hybrid materials? This issue was guest edited by Pierre Rabu and Andreas Taubert and contained a broad range of high quality articles.  

You may also be interested in the current issue of Chem Soc Rev, a themed issue on this topic, with guest editors Clément Sanchez, Kenneth Shea and Susumu Kitagawa. The issue contains 33 tutorial and critical reviews, highlighting exciting new achievements in hybrid materials research.

Joanne Thomson, Deputy Editor of Chem Soc Rev will be attending the Hybrid Materials conference in Strasbourg in March. Let her know if you would like to meet up to discuss RSC Publishing!

 

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The latest issue of Journal of Materials Chemistry is out now!

Journal of Materials Chemistry issue 7 outside front coverThe paper featured on the outside front cover is Self-assembly and charge transport properties of a benzobisthiazole end-capped with dihexyl thienothiophene units (Greg J. McEntee, Filipe Vilela, Peter J. Skabara, Thomas D. Anthopoulos, John G. Labram, Steve Tierney, Ross W. Harrington and William Clegg, J. Mater. Chem., 2011, 21, 2091-2097). The paper reports thin-film studies and OFEt characteristics for a rigid, planar conjugated molecule, BDHTT-BBT. The authors say that this material exhibits liquid crystal properties in its thin-film state.

Journal of Materials Chemistry inside front cover issue 7 2011Unique hexagonal non-close-packed arrays of alumina obtained by plasma etching/deposition with catalytic performance is the paper highlighted on the inside front cover. (Shuyan Gao, Naoto Koshizaki, Yue Li and Liang Li, J. Mater. Chem., 2011, 21, 2087-2090.) This paper reports a hexagonal-non-close-packed alumina array with hierarchical micro-/nano-structures fabricated by plasma etching/deposition that acts as a catalyt in ethyl acetoacetate isomerization.

Journal of Materials Chemistry issue 7 2011 back coverThe back cover showcases the work of David Muñoz-Rojas, Judith Oró-Solé, Omar Ayyad and Pedro Gómez-Romero (Shaping hybrid nanostructures with polymer matrices: the formation mechanism of silver–polypyrrole core/shell nanostructures; J. Mater. Chem., 2011, 21, 2078-2086). In the paper the team show that a polypyrrole matrix forming around suspended Ag2O particles in a pyrrole solution under hydrothermal conditions is key for the formation of tortuous Ag@PPy nanostructures.

You can read the whole issue here:

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Hot Articles on quantum dots for in vivo deep tissue imaging and microfluidic approaches to synthesize anisotropic elongated particles

Graphical abstract: The one-pot synthesis of core/shell/shell CdTe/CdSe/ZnSe quantum dots in aqueous media for in vivo deep tissue imagingThe one-pot synthesis of core/shell/shell CdTe/CdSe/ZnSe quantum dots in aqueous media for in vivo deep tissue imaging. Shohei Taniguchi, Mark Green, Sarwat B. Rizvi and Alexander Seifalian, J. Mater. Chem., 2011, DOI: 10.1039/C0JM03527K, Paper (Advance Article)

Water soluble, near infrared emitting CdTe/CdSe/ZnSe quantum dots have been synthesized in a simple one-pot procedure. The team of scientists based at King’s College London and University College London in the UK, say the emission wavelength could be tuned from 530 nm (original CdTe core) to 670 nm. To demonstrate the effectiveness the quantum dots were used in subcutaneous deep tissue monitoring.

Graphical abstract: Controllable synthesis of anisotropic elongated particles using microvalve actuated microfluidic approachControllable synthesis of anisotropic elongated particles using microvalve actuated microfluidic approach. Qingquan Zhang, Shaojiang Zeng, Bingcheng Lin and Jianhua Qin, J. Mater. Chem., 2011, DOI: 10.1039/C0JM04033A (Advance Article)

The team from the Dalian Institute of Chemical Physics, China, showcase a method to synthesize anisotropic elongated particles via the combination of a droplet based microsphere synthesis and colloidal assembly in a microchannel. The team claim’s that the method is flexible and easy to operate and could find applications in rheological modifiers and drug delivery carrier design.Follow Journal of Materials Chemistry on Twitter

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