Archive for the ‘News’ Category

Breaking zirconacycles is hard to do

In their recent paper in Dalton Transactions, Erker and co-workers describe B(C6F5)3 as an unorthodox probe for the detection of σ ligand character and allenoid-type bonding in substituted zirconocenes.

Chemists have studied the strong Lewis acid, B(C6F5)3 for the past decade, particularly for its uses in frustrated Lewis pairs (FLPs). This small molecule has, however, gained popularity in other areas of chemistry. In catalysis, B(C6F5)3 is commonly employed to generate cationic metal centres by alkyl group abstraction (σ-ligand abstraction) to activate molecular pre-catalysts for use in polymerisation.

Zirconocene cleavage

Expanding the scope beyond alkyl groups, Erker and co-workers showed that B(C6F5)3 can mediate cleavage of Zr-C(sp3) bonds in zirconacycles, creating unique allene coordination complexes. In one instance, they used an unsubstituted zirconacycloallenoid (Zr-CH2-) to synthesise a zwitterionic (η2-allenyl)zirconocene with an allene bond angle close to linearity.

In a second case, they reacted a 4-phenyl substituted zirconacycloallenoid (Zr-CHPh-) to produce a zwitterionic allene-coordinated zirconocene.

In demonstrating such reactivity, the authors lead the way for B(C6F5)3 to act as a standard probe for detecting latent σ ligand character in other molecules.

Interested in finding out more? Read the full article:

Reaction of Five-membered Zirconacycloallenoids with the Strong Lewis Acid B(C6F5)3
Gerald Kehr, Gerhard Erker, Constantin Gabriel Daniliuc, Birgit Wibbeling and Georg Bender
Dalton Trans. 2014, DOI: 10.1039/C4DT01137F


Marcus Drover Marcus Drover is a Ph.D. student, co-supervised by Professors Laurel Schafer and Jennifer Love at the University of British Columbia. His research is focused on the preparation of low-coordinate RhI and IrI complexes for use in small-molecule reactivity. He grew up in St. John’s, Newfoundland and graduated from Memorial University (MUN) before beginning graduate school in 2012.
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HOT articles for July

July brings us a new batch of HOT articles – free to access for 4 weeks only!

Mechanism of water oxidation by non-heme iron catalysts when driven with sodium periodate
Alexander R. Parent, Takashi Nakazono, Shu Lin, Satoshi Utsunomiya and Ken Sakai
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01188K

Graphical Abstract

Free to access until 13th August 2014


Hybrid photocatalysts using graphitic carbon nitride/cadmium sulfide/reduced graphene oxide (g-C3N4/CdS/RGO) for superior photodegradation of organic pollutants under UV and visible light
Rajendra C. Pawar, Varsha Khare and Caroline Sunyong Lee
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01278J

Graphical Abstract

Free to access until 13th August 2014


NAMI-A is highly cytotoxic toward leukaemia cell lines: evidence of inhibition of KCa 3.1 channels
Serena Pillozzi, Luca Gasparoli, Matteo Stefanini, Mirco Ristori, Massimo D’Amico, Enzo Alessio, Federica Scaletti, Andrea Becchetti, Annarosa Arcangeli and Luigi Messori
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01356E

Graphical Abstract

Free to access until 7th August 2014


Shape evolution of Au nanoring@Ag core–shell nanostructures: diversity from a sole seed
Jingsong Sun, Jindi Wang, Ying Zhang, Pengbo Wan, Liang Luo, Feng Wang and Xiaoming Sun
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00992D

Graphical Abstract

Free to access until 4th August 2014


Aqueous stability of alumina and silica perhydrate hydrogels: experiments and computations
Yitzhak Wolanov, Avital Shurki, Petr V. Prikhodchenko, Tatiana A. Tripolskaya, Vladimir M. Novotortsev, Rami Pedahzur and Ovadia Lev
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01024H 

Graphical Abstract
  

Free to access until 4th August 2014

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Hang on to your carbene

What we think of as “organic chemistry” doesn’t often focus on the structure and bonding environments of the carbon atom, unlike inorganic chemistry which often does so with heteroatoms.  So I don’t think I’m going far out on a limb when I say that perhaps the key development in the structure and bonding of carbon over the last quarter century has been the isolation and use of the persistent carbene. 

Arduengo carbene

Arduengo carbene

A carbene is a divalent carbon atom possessing two electrons.  Once thought to be unisolable, its history is recent enough that almost all important figures in its development are not only still living to this day, but still working.  Ron Breslow proposed that carbenes could be isolated in 1957, Guy Bertrand isolated a liquid dicarbene in 1989 and, in 1991, Anthony Arduengo reported the first comprehensive solid-state data of the type of carbene that now bears his name (pictured above).  

So why waste the words of a short post blog on historical perspective?

Because the uses of the carbene have fallen almost entirely in one direction.  Primarily, the carbene has been used as a strong s 2-electron donor – attached to many transition metal atoms it forms very stable complexes, and it is relatively easy to vary its size. 

Only recently have the uses of the carbene diverged. 

In a recent Dalton Transactions paper, Arnold, Love and co-workers present work on labile carbenes tethered to rare earth metals by an alkoxy arm.  On rare earth metals – which are much harder Lewis acids than late transition metals – the soft carbene donor and hard metal acceptor are poorer matches.  Thus the carbon-metal bond may break, freeing the carbene for reactivity, while the hard alkoxy arm keeps the ligand tethered to the metal.

carbene reactivity

Reactivity of tethered alkoxycarbene complexes 

The authors present some examples of reactivity, including co-operative activation of pyrroles and alkynes by the carbene and metal centres, as well as outer-sphere interactions in the form of hydrogen bonding between pyrroles and the metal-bound O atom in solution.   Despite these being small steps, they are nonetheless important if the carbene is to find new roles outside stabilising late transition metal centres.

Interested in finding out more? Read the full paper:

Homo- and heteroleptic alkoxycarbene f-element complexes and their reactivity towards acidic N–H and C–H bonds
Polly L. Arnold, Thomas Cadenbach, Isobel H. Marr, Andrew A. Fyfe, Nicola L. Bell, Ronan Bellabarba, Robert P. Tooze and Jason B. Love
Dalton Trans., 2014, DOI10.1039/C4DT01442A


Ian Mallov Ian Mallov is currently a Ph.D. student in Professor Doug Stephan’s group at the University of Toronto. His research is focused on synthesizing new Lewis-acidic compounds active in Frustrated Lewis Pair chemistry. He grew up in Truro, Nova Scotia and graduated from Dalhousie University and the University of Ottawa, and worked in chemical analysis in industry for three years before returning to grad school.
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Enzyme-Inspiration for a New Nanoswitch

Enzymes function as biological catalysts in a wide array of reactions which are essential for sustaining life. They are almost always large protein molecules which adopt complex three dimensional structures, yet are able to remain structurally dynamic in order to allow the function of the enzyme to be switched on and off.

This feature allows an enzyme’s catalytic activity to be active only when required in the metabolic pathway in which it is involved. For this reason, enzymes have long been a source of inspiration to researchers involved in the design and synthesis of artificial molecular switches and machines.

SARS-CoV 3CLpro is a protease enzyme which is involved in the replication and transcription process of the human coronavirus, the virus which causes severe acute respiratory syndrome (SARS). This enzyme is catalytically inactive as a monomer and only functions as a catalyst when it is bound with another monomer in a complex called a homodimer.

Both crystallographic and mutation studies have implicated several amino acid residues in the dimerization process, however the exact mechanism of dimer formation and how this activates the enzyme’s catalytic activity is still unconfirmed.

 Nanoswitch mechanism 

 Scheme 1. Switching between open and close conformations of nanoswitch 1 in response to metal ion addition

Drawing inspiration from this monomer-dimer on-off mechanism, Schmittel and co-workers have devised a molecular switch capable of toggling between monomeric and dimeric forms in response to the addition of different metal ions. With no metal ions present, the triangular framework adopts the ‘OPEN-I’ conformation (Scheme 1). Upon the addition of copper(I) ions, the two pyridine-based ligands come into proximity to mutually coordinate the metal.

This changes the conformation of the framework to the ‘CLOSE’ state. Addition of iron(II) ions to the ‘CLOSE’ state again changes the molecular conformation, as the iron(II) ions occupy the terpyridine moiety and the copper(I) ions move to occupy only the shielded phenanthroline ligand.

This both forms a homoleptic dimer, as the iron(II) ions can coordinate two terpyridine moieties simultaneously from two different molecules, and creates a coordinatively unsaturated copper species which acts as a catalyst for a cyclopropanation reaction. The authors impressively demonstrate the reversibility of each step, with the removal of metal ions changing the framework back to its uncoordinated conformation.

In this way, they have successfully made a molecular switch which responds to a metal ion signal (Fe2+) and turns a catalytic complex on and off. Like SARS-CoV 3CLpro enzyme, the catalytically active state is the homodimer, with the monomeric form being catalytically inactive.

To find out more, read the full article:

A monomer-dimer nanoswitch that mimics the working principle of the SARS-CoV 3CLpro enzyme controls copper-catalysed cyclopropanation
Soumen De, Susnata Pramanik and Michael Schmittle
Dalton Trans. 2014, DOI:10.1039/c4dt01508h


   Dr C. Liana Allen is currently a post-doctoral research associate in the group of Professor Scott Miller at Yale University, where she works on controlling the enantio- or regioselectivity of reactions using small peptide catalysts. Liana received her Ph.D. in organic chemistry at Bath University with Professor Jonathan Williams, where she worked on developing novel, efficient syntheses of amide bonds.
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HOT articles in June

Take a look at our new HOT articles for the month of June and let us know your thoughts below. Remember, these are ALL free to access for four weeks!

Lithium heterocuprates: the influence of the amido group on organoamidocuprate structures
Roberta Bomparola, Robert P. Davies, Stefan Hornaeur and Andrew J. P. White
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00965G

Graphical Abstract

Free to access until 30th July 2014


Bent and planar structures of μ–η2:η2-N2 dinuclear early transition metal complexes
Xuelu Ma, Yanhui Tang and Ming Lei
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00646A

Graphical Abstract

Free to access until 30th July 2014


Ligand-based photooxidations of dithiomaltolato complexes of Ru(II) and Zn(II): photolytic CH activation and evidence of singlet oxygen generation and quenching
Britain Bruner, Malin Backlund Walker, Mukunda M. Ghimire, Dong Zhang, Matthias Selke, Kevin K. Klausmeyer, Mohammad A. Omary and Patrick J. Farmer
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00961D

Graphical Abstract

Free to access until 15th July 2014


Homo- and heteroleptic alkoxycarbene f-element complexes and their reactivity towards acidic N–H and C–H bonds
Polly L. Arnold, Thomas Cadenbach, Isobel H. Marr, Andrew A. Fyfe, Nicola L. Bell, Ronan Bellabarba, Robert P. Tooze and Jason B. Love
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01442A

Graphical Abstract

Free to access until 15th July 2014


Syntheses, structures and flexible coordination of sterically demanding di- and “tri”-lithiated methandiides
Christian P. Sindlinger and Andreas Stasch
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01185F

Graphical Abstract

Free to access until 15th July 2014


An unusual chiral 3D inorganic connectivity featuring a {Pb18} wheel: rapid and highly selective and sensitive sensing of Co(II)
Yun-Hu Han, Chong-Bin Tian and Shao-Wu Du
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00905C

Graphical Abstract

Free to access until 15th July 2014


Versatile redox reactivity of triaryl-meso-substituted Ni(II) porphyrin
Abdou K. D. Dimé, Charles H. Devillers, Hélène Cattey and Dominique Lucas
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00221K

Graphical Abstract

Free to access until 8th July 2014


Predicting the spin state of paramagnetic iron complexes by DFT calculation of proton NMR spectra
Andrea Borgogno, Federico Rastrelli and Alessandro Bagno
Dalton Trans., 2014, 43, 9486-9496
DOI: 10.1039/C4DT00671B

Graphical Abstract

Free to access until 8th July 2014


Photoreduction and light-induced triplet-state formation in a single-site fluoroalkylated zinc phthalocyanine
Hans Moons, Andrei Loas, Sergiu M. Gorun and Sabine Van Doorslaer
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00621F

Graphical Abstract

Free to access until 8th July 2014


Reversible cargo shipping between orthogonal stations of a nanoscaffold upon redox input
Soumen K. Samanta, Anup Rana and Michael Schmittel
Dalton Trans., 2014, 43, 9438-9447
DOI: 10.1039/C4DT00849A

Graphical Abstract

Free to access until 8th July 2014


Benzo annulated cycloheptatriene PCP pincer iridium complexes
Wolfgang Leis, Sophie Wernitz, Benedikt Reichart, David Ruckerbauer, Johannes Wolfram Wielandt and Hermann A. Mayer
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00885E

Graphical Abstract

Free to access until 8th July 2014


Induced circular dichroism of polyoxometalates via electrostatic encapsulation with chiral organic cations
Yizhan Wang, Lei Shi, Yang Yang, Bao Li and Lixin Wu
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00866A

Graphical Abstract

 Free to access until 8th July 2014


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Top 10 Dalton Transactions most downloaded articles

During the 1st quarter of the year (the months of January, February & March) the top 10 most downloaded Dalton Transactions articles were:

Chloride ion impact on materials for light-emitting electrochemical cells
Gabriel E. Schneider, Henk J. Bolink, Edwin C. Constable, Cathrin D. Ertl, Catherine E. Housecroft, Antonio Pertegàs, Jennifer A. Zampese, Andreas Kanitz, Florian Kessler and Sebastian B. Meier
Dalton Trans., 2014, 43, 1961-1964
DOI: 10.1039/C3DT53229A

Syntheses, topological analyses, and NLO-active properties of new Cd(II)/M(II) (M = Ca, Sr) metal–organic frameworks based on R-isophthalic acids (R = H, OH, and t-Bu)  
Jian-Di Lin, Shu-Ting Wu, Zhi-Hua Li and Shao-Wu Du 
Dalton Trans., 2010, 39, 10719-10728 
DOI: 10.1039/C0DT00390E 

Nitrogen defects from NH3 in rare-earth sesquioxides and ZrO2  
Jonathan M. Polfus, Truls Norby and Reidar Haugsrud 
Dalton Trans., 2011, 40, 132-135 
DOI: 10.1039/C0DT01068E  

Recent progress in the synthesis of inorganic nanoparticles  
C. N. R. Rao, H. S. S. Ramakrishna Matte, Rakesh Voggu and A. Govindaraj 
Dalton Trans., 2012, 41, 5089-5120 
DOI: 10.1039/C2DT12266A     
  
Shape-controlled synthesis and catalytic application of ceria nanomaterials  
Dengsong Zhang, Xianjun Du, Liyi Shia and Ruihua Gao 
Dalton Trans., 2012, 41, 14455-14475 
DOI: 10.1039/C2DT31759A     

Organometal halide perovskites as useful materials in sensitized solar cells  
Surya Prakash Singh and P. Nagarjuna 
Dalton Trans., 2014, 43, 5247-5251 
DOI: 10.1039/C3DT53503G  

Synthesis, crystal structure and EPR spectroscopic analysis of novel copper complexes formed from N-pyridyl-4-nitro-1,8-naphthalimide ligands  
Jonathan A. Kitchen, Paulo N. Martinho, Grace G. Morgan and Thorfinnur Gunnlaugsson 
Dalton Trans., 2014, 43, 6468-6479 
DOI: 10.1039/C3DT53323A  

Metal–organic frameworks in mixed-matrix membranes for gas separation  
Harold B. Tanh Jeazet, Claudia Staudt and Christoph Janiak 
Dalton Trans., 2012, 41, 14003-14027 
DOI: 10.1039/C2DT31550E  

A colorimetric organic chemo-sensor for Co2+ in a fully aqueous environment  
Gyeong Jin Park, Yu Jeong Na, Hyun Yong Jo, Seul Ah Lee and  Cheal Kim 
Dalton Trans., 2014, 43, 6618-6622 
DOI: 10.1039/C4DT00423J  

Zinc and cobalt complexes based on tripodal ligands: synthesis, structure and reactivity toward lactide  
Mathieu J.-L. Tschan, Jia Guo, Sumesh K. Raman, Emilie Brulé, Thierry Roisnel, Marie-Noelle Rager, Rémi Legay, Guillaume Durieux, Baptiste Rigaud and Christophe M. Thomas 
Dalton Trans., 2014, 43, 4550-4564 
DOI: 10.1039/C3DT52629A

Like what you read? If so, please comment below.

If you’d like to submit your work to Dalton Transactions, you can do so by using this direct link: http://mc.manuscriptcentral.com/dalton.

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Salt lakes worth their lithium

Researchers in Japan have demonstrated the exceptional potential of a hydrated titanium oxide to extract lithium from salt lake brine collected from Salar de Uyuni in Bolivia, the world’s largest salt flat.  

The high levels of magnesium and sulfate in Uyuni brine would create difficulties if it was processed by conventional techniques © Shutterstock

The high levels of magnesium and sulfate in Uyuni brine would create difficulties if it was processed by conventional techniques © Shutterstock

Demand for lithium is growing alongside the development of lithium ion batteries. This strain on scarce supplies puts the cost and effectiveness of current methods for harvesting lithium into question.

Interested? Read the full article at Chemistry World.

The original article can be read below:

Lithium recovery from salt lake brine by H2TiO3
Ramesh Chitrakar, Yoji Makita, Kenta Ooi and Akinari Sonoda
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00467A

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Hodgkin’s Nobel Prize remembered

The Royal Society of Chemistry has awarded a National Chemical Landmark blue plaque to the University of Oxford Inorganic Chemistry Laboratory, to celebrate the 50th anniversary of Britain’s first female Nobel Prize winner.

Chief Executive of the Royal Society of Chemistry, Dr Robert Parker, spoke at the plaque presentation and said: “I am delighted to be here again, to honour and celebrate the work of Dorothy Crowfoot Hodgkin. 

Dorothy Crowfoot Hodgkin plaque

“It has been 50 years since she received the Nobel Prize in Chemistry, and so I am delighted to mark the occasion by awarding a new plaque, one that will inspire those that read its message and demonstrate the valuable work that takes place here at the Inorganic Chemistry Laboratory, in Oxford.”

Dorothy Hodgkin won the Nobel Prize “for her determinations by X-ray techniques of the structures of important biochemical substances”.

Amongst her most significant discoveries are the confirmation of the three-dimensional structures of penicillin, Vitamin B12 and insulin.

An award symposium to mark the presentation saw Professors Susan Lea , Paul Raithby and Andrew Goodwin discussing their work in the field of crystallography, and how the field has changed in the 50 years since Hodgkin’s Nobel Prize.

The audience included Professor Philip Mountford, Head of Inorganic Chemistry and Chair of the Dalton Transactions Editorial Board, as well as some of Dorothy’s former students and those they have gone on to teach

2014 is International year of Crystallography and the events at Oxford’s Inorganic Chemistry Laboratory form part of the year-long celebration.

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HOT articles for May!

Check out our new HOT articles for May and keep on checking as these are updated every week and more importantly – free to access for 4 weeks!

A new family of Ln7 clusters with an ideal D3h metal-centered trigonal prismatic geometry, and SMM and photoluminescence behaviors
Eleni C. Mazarakioti, Katye M. Poole, Luis Cunha-Silva, George Christou and Theocharis C. Stamatatos
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00976B

Graphical Abstract

Free to access until 10th June 2014


Enhanced photocatalytic CO2-reduction activity of electrospun mesoporous TiO2 nanofibers by solvothermal treatment
Junwei Fu, Shaowen Cao, Jiaguo Yu, Jingxiang Low and Yongpeng Lei
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00181H

Graphical Abstract

Free to access until 10th June 2014


Towards a comprehensive understanding of the chemical vapor deposition of titanium nitride using Ti(NMe2)4: a density functional theory approach
Kaushik Sen, Tahamida Banu, Tanay Debnath, Deepanwita Ghosh and Abhijit K. Das
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00690A

Graphical Abstract

Free to access until 3rd June 2014


Coordination chemistry of sterically encumbered pyrrolyl ligands to chromium(II): mono(pyrrolyl)chromium and diazachromocene formation
Markus Kreye, Constantin G. Daniliuc, Matthias Freytag, Peter G. Jones and Marc D. Walter
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00533C

Graphical Abstract

Free to access until 3rd June 2014


A study of the optical properties of metal-doped polyoxotitanium cages and the relationship to metal-doped titania
Yaokang Lv, Jun Cheng, Peter D. Matthews, Juan Pedro Holgado, Janina Willkomm, Michal Leskes, Alexander Steiner, Dieter Fenske, Timothy C. King, Paul T. Wood, Lihua Gan, Richard M. Lamberta and Dominic S. Wright
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00555D

Graphical Abstract

Free to access until the 29th May 2014


Activation of the C–N bond of N-heterocyclic carbenes by inorganic elements
Kalon J. Iversen, David J. D. Wilson and   Jason L. Dutton
Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00946K

Graphical Abstract

Free to access until the 29th May 2014


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Gutsy Chemistry Yields Insight Into Reductive Elimination at Rh

Posted on behalf of Ian Mallov, web writer for Dalton Transactions

Reading the chemical literature as a synthetic chemist, I can often empathize with the story of the practical challenges which underlies the research story in a paper.  This article from Gunnoe and co-workers certainly left me with an appreciation for the gutsy way in which the researchers overcame significant challenges to the usual synthetic and analytical techniques of the inorganic chemist to present some hard-won gains on the reductive elimination chemistry of rhodium.

Reductive functionalisation of a Rh-Me bond

The power of reductive elimination – inducing two chemical moieties bonded to a central atom to leave without one of their electrons, resulting in a formal gain of electrons by this central atom – lies in its ability to fuse together the two groups leaving. In this way chemical bonds which are difficult or impossible to form by other means can be created.  When the elimination of one group breaks a metal-carbon bond, the possibility to form a carbon-X bond with the other group reductively-eliminated, and thus functionalize a carbon centre, is particularly attractive.

Such is the technique the Gunnoe group present here.  Much more commonly used in platinum chemistry, they prove this approach to be applicable to rhodium chemistry also, inducing reductive elimination of CH3 and a range of halides or pseudo-halides.  While the CH3-X products formed are useful only as a proof of principle, the proof was a result of overcoming significant challenges. 

The Rh-terpyridine complex ultimately coaxed to undergo reductive CH3-X elimination was so insoluble that they were unable to obtain a NMR spectrum, much less an x-ray crystal structure, and had to trust that a combustion analysis supporting their hypothesized product was evidence enough to proceed.  Then, the hoped-for reductive elimination did not occur until electron-withdrawing NO2 groups were installed on the terpyridine backbone, the reaction was heated, and the solvent changed to CD3NO2 (certainly not the first solvent one would have tried).  Moreover, the CH3-X products formed were gases, making it very difficult to quantify the amount produced.

Nonetheless, their persistent tweaks of the organometallic complex itself, aided by computational thermodynamic data and the use of second-choice analytical techniques when necessary yielded insight into Rh reductive elimination.

Find out more and download the article now:

Reductive functionalization of a rhodium(III)–methyl bond by electronic modification of the supporting ligand
M. E. O’Reilly, D. R. Pahls, J. R. Webb, N. C. Boaz, S. Majumdar, C. D. Hoff, J. T. Groves, T. R. Cundari and T. B. Gunnoe
Dalton Trans., 2014, DOI10.1039/C4DT00234B


Ian Mallov Ian Mallov is currently a Ph.D. student in Professor Doug Stephan’s group at the University of Toronto. His research is focused on synthesizing new Lewis-acidic compounds active in Frustrated Lewis Pair chemistry. He grew up in Truro, Nova Scotia and graduated from Dalhousie University and the University of Ottawa, and worked in chemical analysis in industry for three years before returning to grad school.
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