Lewis Pair polymerization

This article is HOT as recommended by the referees. And we’ve made it free to access for 4 weeks.

In this HOT article, Chen et al. extend their previous work to present a combined experimental and computational investigation of Lewis Pair polymerization incorporating 11 Lewis acids and 10 achiral and chiral Lewis bases, for the polymerization of 12 different types of monomers.

Read more about the polymerization mechanism for FREE for 4 weeks at:

Lewis pair polymerization by classical and frustrated Lewis pairs: acid, base and monomer scope and polymerization mechanism
Yuetao Zhang, Garret M. Miyake, Mallory G. John, Laura Falivene, Lucia Caporaso, Luigi Cavallo and Eugene Y.-X. Chen
Dalton Trans., 2012, Advance Article
DOI: 10.1039/C2DT30427A

This article will form part of a themed issue on Frustrated Lewis Pairs guest edited by Douglas W. Stephan.  Other papers in this issue include:

Exchange chemistry of tBu3P(CO2)B(C6F5)2Cl
Rebecca C. Neu, Gabriel Ménard and Douglas W. Stephan

Fixation of carbon dioxide and related small molecules by a bifunctional frustrated pyrazolylborane Lewis pair
Eileen Theuergarten, Janin Schlösser, Danny Schlüns, Matthias Freytag, Constantin G. Daniliuc, Peter G. Jones and Matthias Tamm

[2.2]Paracyclophane derived bisphosphines for the activation of hydrogen by FLPs: application in domino hydrosilylation/hydrogenation of enones
Lutz Greb, Pascual Oña-Burgos, Adam Kubas, Florian C. Falk, Frank Breher, Karin Fink and Jan Paradies

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