HOT Article: Pd(0) catalyst precursors

This HOT Article presents the facile synthesis of Pd(0) complexes that could be utilized as catalyst precursors.  The weak donor power of the PR2Cl ligand may make this route a simple entry to the reactive “Pd(NHC)” moiety for catalysis applications.

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Generation of [(IPr)Pd(PR2Cl)] complexes via P–Cl reductive elimination
Bennett J. Tardiff, Kevin D. Hesp, Michael J. Ferguson and Mark Stradiotto
Dalton Trans., 2012, Advance Article
DOI: 10.1039/C1DT11910A

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