This HOT Article presents the facile synthesis of Pd(0) complexes that could be utilized as catalyst precursors. The weak donor power of the PR2Cl ligand may make this route a simple entry to the reactive “Pd(NHC)” moiety for catalysis applications.
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Generation of [(IPr)Pd(PR2Cl)] complexes via P–Cl reductive elimination
Bennett J. Tardiff, Kevin D. Hesp, Michael J. Ferguson and Mark Stradiotto
Dalton Trans., 2012, Advance Article
DOI: 10.1039/C1DT11910A
