Dalton Transactions issue 19 published

Check out the cover articles in Dalton Transactions issue 19

The outside cover features work from the Leznoff group.  Four new [AuBr2(CN)2]-based coordination polymers, Zn(pyz)(NCMe)2[AuBr2(CN)2]2 (1; pyz = pyrazine), Co(pyz)[AuBr2(CN)2]2·H2O (2) and [M(bipy)2(AuBr2(CN)2)][nBu4N][AuBr2(CN)2]2 (bipy = 4,4′-bipyridine), where M = Co (5) and Zn (6), were synthesized and three of them structurally characterized. 1 forms 1-D chains connected by pyz ligands while isostructural 5 and 6 form 3-D frameworks via [AuBr2(CN)2] and bipy linkers.

Read more at:

Thermally triggered reductive elimination of bromine from Au(III) as a path to Au(I)-based coordination polymers
Jeffrey S. Ovens and Daniel B. Leznoff
Dalton Trans., 2011, 40, 4140-4146
DOI: 10.1039/C0DT01772H

The inside cover originates from two articles by the Kumar group based on chemosensors.

For more details see:

Ratiometric detection of Hg2+ ions: an allosterically synchronized Hg2+/Li+ switch based on thiacalix[4]crown
Manoj Kumar, Naresh Kumar and Vandana Bhalla
Dalton Trans., 2011, 40, 5170-5175
DOI: 10.1039/C1DT10093A

Structural and magnetic properties of three novel complexes with the versatile ligand 5-methyl-1,2,4-triazolo[1,5-a]pyrimidin-7(4H)-one
Ana B. Caballero, Antonio Rodríguez-Diéguez, Luis Lezama, Elisa Barea and Juan M. Salas
Dalton Trans., 2011, 40, 5180-5187
DOI: 10.1039/C0DT01416H

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