In this HOT article, Rosenthal and co-workers present studies on the application of group 4 metal complexes, in particular metallocene alkyne complexes and metal amides, for the catalytic dehydrogenation of dimethylamine borane. In this context, the catalytic evolution of hydrogen from stable hydrogen storage materials has become increasingly important.
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Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds
Torsten Beweries, Sven Hansen, Monty Kessler, Marcus Klahn and Uwe Rosenthal
Dalton Trans., 2011, Advance Article
DOI: 10.1039/C1DT10366K, Communication