Scientists normally want to stop their metal–organic frameworks (MOFs) from interpenetrating. But after realising the drawbacks of these entangled structures could actually be benefits they now want to find ones that definitely will.
It’s hard to mention MOFs without mentioning their pores. These pores and the potential created by their massive surface area have had scientists daydreaming about their possible applications for years. But these pores can easily clog up with sub-lattices, rendering them useless. Or so they thought. Interpenetrated MOFs are very strong and they can still have pores – with a much more specific size, which could be quite handy.
Interested? The full story can be read in Chemistry World.
The original article can be read below and is free to access until 18th September 2017
Discovery of hypothetical hetero-interpenetrated MOFs with arbitrarily dissimilar topologies and unit cell shapes
K B Sezginel, T Feng and C E Wilmer*
CrystEngComm, 2017, 19, 4497-4504
Congratulations to the CrystEngComm poster prize winners who were awarded at The 4th Crystal Engineering and Emerging Materials Workshop of Ontario and Quebec (CEMWOQ-4). The workshop was held in Ontario, Canada from the 26th – 28th May 2017. Christer Aakeroy our Associate Editor attended as a plenary lecturer and was on hand to award the prizes.
The winners were presented accordingly:
1st Place Undergraduate Poster Award: Junghoon Ko, University of Windsor, for “Discotic Liquid Crystals with Internal Side Chains as Potential Organic Semi-Conductors”
2nd Place Graduate Poster Award: Mitchell Nascimento, University of Windsor, for “Expanding the Family of Palladium-DTDA Metal Complexes”
2nd Place Undergraduate Poster Award: Austin Peach, University of Windsor, for “Applications of 35Cl SSNMR for the study of HCl Pharmaceutical Cocrystals”
The workshop enables an easy exchange of ideas, expertise and information and serves as an educational event for students. It also supports/creates new collaborations between research groups. There are plenary and oral presentations, and a poster session with opportunity for discussion within the program. A training workshop on the day before the main meeting is included, on a topic relevant to one or more of the existing themes of the meeting.
Further information on the most recent meeting, and links to other previous meetings, can be viewed at this website.
Weather and climate influence solid state reactions in previously unrealised ways. So say scientists who have found a mysterious liquid phase at the interface between solids when investigating mechanochemical synthesis.
Mechanochemical reactions are performed by grinding two solid reactants together without a solvent. They are often touted as a green alternative to traditional synthesis, and occur via complex pathways quite different to reactions in solution. Humans have used mechanochemistry since time immemorial: to create fire from the friction between two pieces of wood, in the process of ball milling since the industrial revolution, and to prepare powders for pharmaceuticals and rocket propellants.
The full article can be read in Chemistry World.
The original article can be read below and is open access
Inadvertent liquid assisted grinding: a key to “dry” organic mechano-co-crystallisation?
I A Tumanov et al,
CrystEngComm, 2017, 19, 2830
Congratulations to CrystEngComm prize winners: Bhupinder Sandhu, Yue Qiu and Shane Nichols. They were awarded their prizes at the Midwest Organic Solid State Chemistry Symposium XXVII (MOSSCS) which took place at Kansas State University, USA from the 9th – 10th June 2017. CrystEngComm Associate Editor Christer Aakeroy was on hand to present their certificates.
The MOSSCS symposium provides opportunities for the scientific community to exchange ideas and research results on the organic solid state in a relaxed environment. The symposium involves presentations by graduate students and postdoctoral associates as well as invited lectures on topics of current interest.
Further information about the symposium can be found on their website.
Guoqing Zhang, Xuepeng Zhang and their team at the University of Science and Technology of China first intended to construct a series of organic ligands for water-based acrylic paints. By performing a routine Claisen condensation reaction between a ketone and an ester, they obtained a number of pyridine-substituted β-diketone compounds as fluffy crystals, with varying positions of nitrogen-substitution in the pyridine ring.
Interested? The full story can be read in Chemistry World.
The original article can be read below and is free to access until 9th June 2017:
Curved fractal structures of pyridine-substituted β-diketone crystals
Zongzheng Qian, Dongxue Li, Tongqing Xie, Xuepeng Zhang,* Yang He, Yuejie Ai and Guoqing Zhang*
CrystEngComm, 2017, 19, 2283-2287
Following the success of Peer Review Week in September 2016 (dedicated to reviewer recognition) during which we published a list of our top reviewers, we are delighted to announce that we will continue to recognise the contribution that our reviewers make to the journal by announcing our Outstanding Reviewers each year.
We would like to highlight the Outstanding Reviewers for CrystEngComm in 2016, as selected by the editorial team, for their significant contribution to the journal. The reviewers have been chosen based on the number, timeliness and quality of the reports completed over the last 12 months.
We would like to say a big thank you to those individuals listed here as well as to all of the reviewers that have supported the journal. Each Outstanding Reviewer will receive a certificate to give recognition for their significant contribution.
Professor Dino Aquilano, University of Torino
Dr Timur Atabaev, Seoul National University
Dr Ian Dance, Unversity of New South Wales
Dr Laszlo Fabian, University of East Anglia
Professor Huiging Fan, Northwestern Polytechnical University
Dr Goutam Kole, SRM University
Dr Mahesh Kumar, Indian Institute of Technology Jodhpur
Dr Zheng Ren, University of Connecticut
Dr Dongpeng Yan, Beijing Normal University
Dr Jiatao Zhang, Beijing Institute of Technology
We would also like to thank the CrystEngComm board and the Inorganic community for their continued support of the journal, as authors, reviewers and readers.
If you would like to become a reviewer for our journal, just email us with details of your research interests and an up-to-date CV or résumé. You can find more details in our author and reviewer resource centre
Welcome to CrystEngComm’s newest Editorial board member – Professor Tong-Bu Lu. Professor Lu works at the Institute for New Energy Materials and Low Carbon Technologies, based at the Tianjin University of Technology, China.
His research interests include the recognition and activation of molecules and ions by the macrocyclic compounds; the constructions of porous metal-organic frameworks, and investigation of their properties for gases storages and separation, ions exchange and chiral separation and pharmaceutical polymorphs and cocrystals. He has been recognised as a distinguished Professor in Guangdong Province, China
Please see below a selection of recent articles published by Professor Lu for CrystEngComm:
Interpenetrating metal–organic frameworks
Yun-Nan Gong, Di-Chang Zhong and Tong-Bu Lu
CrystEngComm, 2016, 18, 2596-2606
DOI: 10.1039/C6CE00371K, Highlight
Synthesis and structures of dinuclear cryptates with Zn(II), Cd(II) and Hg(II): tuning the cascade binding mode with metal ions
Feng Yan, Xiao-Mei Zhuang and Tong-Bu Lu
CrystEngComm, 2015, 17, 5832-5840
DOI: 10.1039/C5CE00817D, Paper
Thermodynamics and preliminary pharmaceutical characterization of a melatonin–pimelic acid cocrystal prepared by a melt crystallization method
Yan Yan, Jia-Mei Chen and Tong-Bu Lu
CrystEngComm, 2015, 17, 612-620
DOI: 10.1039/C4CE01921K, Paper
ORCID provides an identifier for individuals to use with their name as they engage in research, scholarship and innovation activities, ensuring authors gain full credit for their work.
Today, we signed their open letter, along with ACS Publications, committing to unambiguous identification of all authors that publish in our journals.
The official press release can be read here.
Congratulations to Mr Asato Mizuno the CrystEngComm presentation prize winner at the 25th Symposium on Organic Crystals which took place from the 18th – 19th September in Koyoto, Japan.
The symposium was organised by the Organic Crystals Division – Chemical Society of Japan. Mr Mizuno’s presentation was titled: ‘Structures and Physical Properties of 3D Crystals Formed by a Triangular π Radical’.